Are PDLCs only available as artificial materials?

Not at all; common examples of natural occurrences of liquid crystals include proteins, soaps, detergents, and even some types of clay.

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Is smart glass/film available in irregular shapes?

Yes, smart glass/film is available in all irregular shapes as you want, including curved glass.

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What is the structure of PDLC glass?

PDLC smart glass is composed of :
Outermost panels of normal float glass (or sometimes acrylic) sandwiched around:
Inner panels of optically clear PET plastic (polyethylene terephthalate), sandwiched around:
ITO (Indium Tin Oxide) which is a transparent conductor, sandwiched around:
a PDLC core comprised of liquid crystal droplets, suspended in a polymer.

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How long time does smart glass/film change from opaque to transparent?

Smart glass/film change in 1/100 second from opaque to transparent and 1/10 second from transparent to opaque.

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What is smart glass comprised?

Smart glass is a laminated glass comprising 2pcs of glass sandwiched in between by an EVA/PVB interlayer.

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How does smart glass/film works?

Smart glass works via electrical signal through activation of switches, sensors etc. Liquid crystal molecules turn to allow light to pass through and glass becomes transparent. It is opaque when not activated.

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Why does PDLC require a polymer?

The polymer allows the liquid crystals to be embedded into a film, which can then be sandwiched between panels of glass or plastic. The polymer has constant optical properties which do not vary across its structure, and hence is considered isotropic.
In contrast, the liquid crystal itself is anisotropic, since its optical characteristics are not constant across its structure, but rather can vary under application of an electric field.

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