Why does PDLC require a polymer?

The polymer allows the liquid crystals to be embedded into a film, which can then be sandwiched between panels of glass or plastic. The polymer has constant optical properties which do not vary across its structure, and hence is considered isotropic.
In contrast, the liquid crystal itself is anisotropic, since its optical characteristics are not constant across its structure, but rather can vary under application of an electric field.

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Why does PDLC glass scatter light?

The liquid crystals change their refractive index in relation to the isotropically transparent polymer in which they are immersed, thereby creating multiple step boundaries throughout the PDLC.
It is this change in refractive index at each boundary which causes light to change course. Since the PDLC material contains millions of liquid crystals, each with a boundary facing a slightly different way, the light is scattered in many directions.
The net effect is to hide whatever is behind the PDLC smart glass.

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What is a Liquid Crystal?

A liquid crystal is a hybrid between (i) a liquid which flows like a fluid and (ii) a crystal which is normally found as a solid, exhibiting short- or long-range symmetry.

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Is smart glass/film available in irregular shapes?

Yes, smart glass/film is available in all irregular shapes as you want, including curved glass.

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Why does PDLC glass scatter light?

The liquid crystals change their refractive index in relation to the isotropically transparent polymer in which they are immersed, thereby creating multiple step boundaries throughout the PDLC.
It is this change in refractive index at each boundary which causes light to change course. Since the PDLC material contains millions of liquid crystals, each with a boundary facing a slightly different way, the light is scattered in many directions.
The net effect is to hide whatever is behind the PDLC smart glass.

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What is smart glass/film?

Smart glass/film is a switchable light control glass that turns a transparent glass to opaque instantaneously and vice versa.

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Why is PDLC considered to be smart?

The smartness of PDLCs is a result of its ability to change its transparency (technically called the transmittance) when an electrical stimulus is applied to it. This is normally by way of an alternating voltage, which exerts an alternating electric field across the PDLC material.
Nevertheless, the PDLC is only as smart as the control system which stimulates the change, which can be driven by a push button switch, a light sensor, or a building automation system.

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